Cybotactic Effect on Nitrogen and Phosphorus Hyperfine Coupling Constants in β-Phosphorylated Nitroxides.

Co-Authors

Gerard Audran, Jean-Patrick Joly, Sylvain R. A. Marque

Citation

Gerard A, Jean-Patrick J, Marque, Cybotactic Effect on Nitrogen and Phosphorus Hyperfine Coupling Constants in ?-Phosphorylated Nitroxides.(2017)Journal of Chemical Engineering And Bioanalytical Chemistry 2(1)

Abstract

Solvent effect is investigated on β-phophorylated nitroxides carrying electron widthdrawing groups exhibiting various steric hindrances. Solvent effect on nitrohen and phosphorus hyperfine coupling constants highlights the entanglement of polar and steric effects on the changes in hyperfine coupling constants.

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