Chemical-substitution-induced successive symmetry descent and structure-property correlation for "114" oxides CaBa1-xSrxZn2Al2O7.


College of Chemistry and Chemical Engineering, Chongqing University, Chongqing, 401331, People's Republic of China. [Email] [Email]


The crystal structures, photoluminescence properties, and transport properties of a series of new "114" oxides CaBa1-xSrxZn2Al2O7 (x = 0-1) were investigated in detail. Careful Rietveld refinements performed on solid solution samples revealed that the structural symmetry of CaBa1-xSrxZn2Al2O7 evolves from hexagonal P63mc (x < 0.2) to trigonal P31c (0.2 ≤ x ≤ 0.6) and then to orthorhombic Pna21 (x > 0.6) with an increase of the Sr2+-content, which is cooperative with the rotation of T1O4 tetrahedra around the c-axis. Eu3+ was used as a local structural probe to gain an insight into the structure, which further corroborated the correctness of the observed structural symmetry descending sequence in CaBa1-xSrxZn2Al2O7. More importantly, the reduction of structural symmetry is also associated with a tendency from layered ordering to complete charge ordering transition for Zn2+/Al3+ cations, which was revealed to have a significant influence on the transport properties. These findings are expected to offer a route to manipulate the physical properties of "114" oxides containing magnetic cations.

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