Construction of magnetic bifunctional β-cyclodextrin nanocomposites for adsorption and degradation of persistent organic pollutants.


State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, PR China. Electronic address: [Email]


Herein, we report a novel magnetic bifunctional β-cyclodextrin nanocomposite (Fe3O4@β-CD-CDI) based on metal coordination, which may be used for adsorption and degradation of persistent organic pollutants in aqueous solution. More importantly, N,N'-carbonyldiimidazole (CDI) functionalized β-CD ligand (β-CD-CDI) was assembled on the surface of Fe3O4 by Zn-N interaction. The results of kinetic and isothermal adsorption model investigation indicated that the adsorption rate and capacity of Fe3O4@β-CD-CDI were better than other materials, suggesting the effective accessibility of adsorption sites. We further confirmed that Fe3O4@β-CD-CDI can be used as heterogeneous catalyst to remove BPA through Fenton-like reaction in the presence of hydrogen peroxide (H2O2). Moreover, the material effectively alleviated the secondary pollution owing to the existence of β-CD inner cavity. This study indicated that the magnetic Fe3O4@β-CD-CDI material has great potential applications in wastewater purification containing persistent organic pollutants.


Adsorption and degradation,Magnetic,Metal coordination,Persistent organic pollutants,β-cyclodextrins nanocomposite,

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