Synergistic Catalysis of Co(OH)2/CuO for the Degradation of Organic Pollutant Under Visible Light Irradiation.


Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi, 830046, China. [Email]


The exploration of advanced water treatment technologies e.g. heterogeneous photocatalysis is the most promising way to address organic pollution issues. Semiconductors based bimetallic photocatalysis with wide bandgap, have displayed splendid degradation performance in the UV light region, but their extension to the visible light/near infra-red region is still a matter of great concern. CuO, Co(OH)2, CoO and Co(OH)2/CuO nanocomposites were synthesized via simple co-precipitation method and further practiced for Rhodamine B (RhB) decomposition by introducing per-sulfate (PS) as a sacrificial agent. Results revealed that Co(OH)2/CuO catalyst had shown robust catalytic activity for RhB photodegradation (degradation time 8 min, k = 0.864 min-1) under light illumination, significantly less (12-60 times) than the other reported bimetallic catalysts. Catalyst also have verified excellent performance for a broader pH range (5-9) with excellent stability. Main reactive species responsible for the photocatalytic reaction were sulfate (SO4•-) and superoxide (O2•) radicals, duly verified by ESR and by using radical scavengers. With outstanding recycling abilities, this is probably the fewer successful attempt for RhB decolorization and can be highly favorable for effluent treatment by using the synergic effect of absorption and photodegradation.

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