SDRP Journal of Nanotechnology & Material Science

ISSN: 2574-1888


Page No: 13-16

Synthesis and Optical Properties of Ethynylene-linked Trisporphyrins


Kazuya Ogawa, Synthesis and Optical Properties of Ethynylene-linked Trisporphyrins(2018)SDRP Journal Of Nanotechnology & Material Science 1(1)


Ethynylene-linked trisporphyrin having aryl substituents was synthesized using Pd-catalyzed cross-coupling reaction. This compound exhibited a large effective two-photon absorption cross section value of 2.2 × 104 GM at 890 nm measured by using a nanosecond Z-scan method, which was almost twice as long as those of the Soret band. The value was 3 times larger than that obtained for trisporphyrin having alkyl groups.


  1. aE. A. Wachter, W. P. Partridge, W. G. Fisher, H. C. Dees, M. G. Petersen, Proc. SPIE-Into. Soc. Opt. Eng. 1998, 3269, 68-74; bJ. D. Bhawalkar, N. D. Kumar, C. F. Zhao, P. N. Prasad, J. Clin. Laser. Med. Surg. 1997, 15, 201-204. PMid:9612170

  2. aD. A. Parthenopoulos, P. M. Rentzepis, Science 1989, 245, 843-845; bJ. H. Strickler, W. W. Webb, Opt. Lett. 1991, 16, 1780-1782. Cross Ref PMid:19784138

  3. Nonlinear Optics of Organic Molecules and Polymers, CRC Press: Boca Raton, 1997. Google Scholar

  4. aR. L. Goyan, D. T. Cramb, Photochem. Photobiol. 2000, 72, 821-827 Link; bM. Drobizhev, A. Karotki, M. Kruk, A. Rebane, Chem. Phys. Lett. 2002, 355, 175-182 Link.

  5. aY. Kobuke, H. Miyaji, J. Am. Chem. Soc. 1994, 116, 4111-4112 Cross Ref; bY. Kobuke, K. Ogawa, Bull. Chem. Soc. Jpn. 2003, 76, 689-708.

    View Article           

  6. aK. Ogawa, A. Ohashi, Y. Kobuke, K. Kamada, K. Ohta, J. Am. Chem. Soc. 2003, 125, 13356-13357 Cross Ref; bK. Ogawa, A. Ohashi, Y. Kobuke, K. Kamada, K. Ohta, J. Phys. Chem. B 2005, 109, 22003-22012. PMid:16853858

  7. Y. Inaba, K. Ogawa, Y. Kobuke, J. Porphyrins Phthalocyanines 2007, 11, 406-417 Google Scholar.

    View Article           

  8. C. Ikeda, Z. S. Yoon, M. Park, H. Inoue, D. Kim, A. Osuka, J. Am. Chem. Soc. 2005, 127, 534-535 Link. PMid:15643872

    View Article      PubMed/NCBI     

  9. D. Y. Kim, T. K. Ahn, J. H. Kwon, D. Kim, T. Ikeue, N. Aratani, A. Osuka, M. Shigeiwa, S. Maeda, J. Phys. Chem. A 2005, 109, 2996-2999. PMid:16833622

    View Article      PubMed/NCBI     

  10. M. Drobizhev, A. Karotki, M. Kruk, N. Z. Mamardashvili, A. Rebane, Chem. Phys. Lett. 2002, 361, 504-512. 00999-5

    View Article           

  11. M. Drobizhev, Y. Stepanenko, A. Rebane, C. J. Wilson, T. E. O. Screen, H. L. Anderson, J. Am. Chem. Soc. 2006, 128, 12432-12433. PMid:16984190

    View Article      PubMed/NCBI     

  12. J. E. Raymond, A. Bhaskar, T. Goodson, N. Makiuchi, K. Ogawa, Y. Kobuke, J. Am. Chem. Soc. 2008, 130, 17212-+. PMid:19053414

    View Article      PubMed/NCBI     

  13. O. Varnavski, J. Raymond, Z. Yoon, T. Yotsutuji, K. Ogawa, Y. Kobuke, T. Goodson, J. Phys. Chem. C 2014, 118, 28474-28481.

    View Article           

  14. aJ. T. Dy, K. Ogawa, A. Satake, A. Ishizumi, Y. Kobuke, Chem. Eur. J. 2007, 13, 3491-3500; bJ. K. Laha, S. Dhanalekshmi, M. Taniguchi, S. Ambroise, J. S. Lindsey, Org. Process Res. Dev. 2003, 7, 799.

  15. aP. Audebert, K. Kamada, K. Matsunaga, K. Ohta, Phys, Lett. 2003, 367, 62; bL. Antonov, K. Kamada, K. Ohta, S. Kamounah, Phys. Chem. Chem. Phys. 2003, 5, 1193.

  16. K. Ogawa, J. Dy, Y. Kobuke, J. Porphyrins Phthalocyanines 2005, 9, 735-744.

    View Article           

  17. J. Tanihara, K. Ogawa, Y. Kobuke, J. Photochem. Photobiol. A 2006, 178, 140-149.

    View Article