In situ deposited hierarchical CuO/NiO nanowall arrays film sensor with enhanced gas sensing performance to H2S.


Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin, 150080, China. Electronic address: [Email]


Hierarchical and heterogeneous CuO/NiO nanowall arrays were in situ grown on ceramic tubes via a facile template-free hydrothermal route, and then were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and nitrogen adsorption-desorption techniques. The resultant composites exhibit network-like CuO/NiO array structures constructed by interconnected porous nanosheets, in which the decoration of CuO nanoparticles in NiO nanowall arrays was confirmed by XRD, XPS and TEM analyses. The 2.84 at % CuO decorated NiO sensor exhibits excellent sensing properties at 133 °C. The response to 5 ppm H2S attains 36.9, which increases as high as 5.6 times compared to the NiO one. The detection limit to H2S is further decreased from 1 ppb for the pure NiO sensor to 0.5 ppb. The CuO/NiO sensor shows a wide linear range from 50 to 1000 ppb, good repeatability, selectivity and long-term stability, which is expected to be a candidate for ppb-level H2S detection in real and complex environment of industrial production. Furthermore, the dominant H2S sensing mechanism is discussed from the view of the homo- and hierarchical architecture of the CuO/NiO arrays as well as the chemical and electronic sensitization effects of CuO decoration.


CuO/NiO nanowall arrays,H(2)S sensor,Hierarchical structure,In situ deposition,

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